Sökresultat
Filtrera
Filtyp
Din sökning på "*" gav 535942 sökträffar
Confirmation of sex pheromone biosynthesis from (16-D3)palmitic acid in the turnip moth using capillary gas chromatography
(16-D3)palmitic acid was applied topically to pheromone glands of the turnip moth. After incubation omega labeled analogues of fatty acid methyl esters and acetates were identified by gas chromatography with flame ionization detection and selected ion monitoring. The pheromone components (Z)-5-decenyl, (Z)-7-dodecenyl- and (Z)-9-tetradecenyl acetate were all biosynthesized from palmitic acid along
Sex pheromone components of Mamestra suasa : chemical analysis, electrophysiological activity, wind tunnel activity and field tests in two European countries
(Z)‐11‐hexadecenyl acetate (Z‐11–16:Ac), (Z)‐11‐hexadecenal (Z‐11–16:Ald), (Z)‐11‐hexadecenol (Z‐11–16:OH) and hexadecanyl acetate (16:Ac) were found in pheromone gland extracts of female Mamestra suasa (Den. et Schiff.) in the relative amounts 100/2/10/5. All four compounds were also present in collections of airborne volatiles from calling females in a 100/7/5/5 ratio. No traces of 14 carbon ald
Sex pheromones and reproductive isolation in four european small ermine moths
Reproductive isolation among four sympatric small ermine moths (Yponomeuta) is analyzed in terms of niches in the sexual communication channel. Potential pheromone components were identified from pheromone gland secretions of Y. evonymellus, Y. cagnagellus, Y. padelius, and Y. vigintipunctatus by gas chromatography with flame ionization and electroantennographic detection and tested for behavioral
Chain-elongated analogues of a pheromone component of the turnip moth, Agrotis segetum. A structure-activity study using molecular mechanics
Chain-elongated analogues of (Z)-dec-5-enyl acetate, a pheromone component of the turnip moth, Agrotis segetum, have been studied. The conformational energies required for the analogues to mimic spatial relationships in the parent molecule, assumed to be crucial for the receptor interaction, were calculated by molecular mechanics (MM2). The calculated energies show a striking correlation with meas
Sex pheromone precursors in two primitive New Zealand tortricid moth species
Female pheromone gland extracts of two primitive New Zealand tortricid species that use (Z)-8-tetradecenyl acetate as a pheromone component were analyzed for pheromone precursors. Both Planotortrix excessana and Ctenopseustis obliquana contained (Z)-8-tetradecenoate as well as large amounts of (Z)-10-hexadecenoate. We propose that (Z)-8-tetradecenyl acetate is synthesized from hexadecanoate (palmi
Full scale tunnel evacuation experiment to determine appropriate emergency exit portal designs in road tunnels
In this paper, the execution and results of an evacuation experiment that was conducted in a road tunnel in Stockholm in 2014 is presented. The primary objective of the experiment was to evaluate the effectiveness of different emergency exit portal designs, and other technical installations/aids in the tunnel, during a fire evacuation in smoke. Based on the results, it is concluded that the emerge
Determination of the Double Bond Position in Monounsaturated Acetates from Their Mass Spectra
A simple method of widespread applicability in determining double bond positions in C12, C14, and C16 straight-chain monounsaturated acetates is presented. The analysis is made with a capillary gas chromatograph coupled to a low-resolution mass spectrometer which is operated in the electron impact mode. No chemical derlvatlzation of the unknowns is needed. Five pairs of selected mass spectral frag
Affordance-based evaluation of signage design for areas of refuge
The evacuation of disabled persons from multi-storey buildings requires, typically, the provision and use o Areas of Refuge (AoR). Building complexity, together with the low level of detail in the regulatory guidance- relating to AoR signage, may lead to inappropriate signage system designs. In turn. this may lead to difficulties in locating and or identifying AoR. This paper illustrates the use o
Individual variation in the pheromone of the turnip moth, Agrotis segetum
Female turnip moths (Agrotis segetum) from a laboratory culture inbred for more than 30 generations, and the offspring (first and third generation) from field-collected insects were analyzed individually for acetates and alcohols in the pheromone gland. Quantitative analysis of individual components was performed at the subnanogram level by gas chromatographymass spectrometry (selected ion monitor
Behavioral responses of male turnip moths, Agrotis segetum, to sex pheromone in a flight tunnel and in the field
The response of individual male turnip moths Agrotis segetum was observed in a sustained flight tunnel to a mixture of decyl acetate, (Z)-5-decenyl acetate, (Z)-7-dodecenyl acetate, and (Z)-9-tetradecenyl acetate in proportions similar to those found in gland extracts from virgin females (0.6: 1:5:2.5). Lures containing 3-30 μg (Z)-5-decenyl acetate proved to be maximally attractive, with approxim
Analysis of moth pheromone acetates by selected ion monitoring using electron impact and chemical ionization mass spectrometry
Mass spectrometric determination of moth pheromone components by means of selected ion monitoring with electron impact and chemical ionization has been evaluated. For the analysis of acetates, chemical ionization with ammonia as reactant gas proved advantageous with respect to sensitivity and selectivity. A quantitative assay for determination of pheromone samples from individual turnip moth femal
Continuous single sensillum recording as a detection method for moth pheromone components in the effluent of a gas chromatograph
ABSTRACT. Single sensillum recordings were made from male antennal pheromone receptors of Agrotis segetum (Schiff.) (Noctuidae) and Adoxophyes orana (F.v.R.) (Tortricidae). A gas chromatograph (GC) was used to prepare and to deliver the odour stimuli. Samples of female abdominal gland extracts were injected into the column of the GC and the responses of the receptor cells to the effluent were reco
SEX PHEROMONE OF THE CONE PYRALID DIORYCTRIA ABIETELLA
Gas chromatographic analyses coupled with electro‐antennographic detection indicated that (Z,E)‐9,11‐tetradecadienyl acetate (Z,E‐9,11–14Ac) is a pheromone component of the cone pyralid Dioryctria abietella. Gas chromatographic − mass spectrometric analyses confirmed the presence of a tetradecadienyl acetate with mass spectrum and retention index identical to Z,E‐9,11–14Ac. A receptor cell sensiti
Fires: fund research for citizen safety
Sex pheromone components of the turnip moth, Agrotis segetum - Chemical identification, electrophysiological evaluation and behavioral activity
Analysis of female abdominal tips of Agrotis segetum by means of GC-MS showed the presence of 13 aliphatic acetates and alcohols. (Z)-7-Dodecenyl acetate was found to be the main component in the extracts at amounts of about 1 ng/female. (Z)-9-Tetradecenyl acetate and (Z)-7-dodecenol were present to the extent of 49 and 19%, respectively, of the main component. Minor components could be identified
Human behaviour in road tunnel safety design: evacuation modelling vs Italian Risk Analysis Method (IRAM)
Road tunnel fires are non-recurrent events which have led the researchers to investigate on the best risk analysis methodology. At the moment, the European Directive 2004/54/EC on minimum safety requirements for tunnels in the Trans-European road network gives only general statements. Consequently, practitioners have often difficulties to define the best way to ensure the desired safety conditions
A Glossary for Research on Human Crowd Dynamics
This article presents a glossary of terms that are frequently used in research onhuman crowds. This topic is inherently multidisciplinary as it includes work in and across computer science, engineering, mathematics, physics, psychology and social science, for example. We do not view the glossary presented here as a collection of finalised and formal definitions. Instead, we suggest it is a snapsho
Developing and validating evacuation models for fire safety engineering
Evacuation models can adopt different approaches for the simulation of human behaviour in fire. This paper provides an overview of the most commonly used modelling methods to represent the evacuation process in a fire scenario. This is presented through a structure matching the engineering time-line model of evacuation. The evacuation model development process is discussed considering both data-dr
”Operation Rimfrost bygger, liksom annat polisiärt arbete, på vetenskaplig grund.”
Den ekonomiska brottsligheten må vara högre i områden som Limhamn och Västra hamnen, men det är brott där polisen oftast inte behöver sätta in massiva razzior, skriver Ardavan Khoshnood, docent i akutsjukvård vid Lunds universitet och kriminolog.Economic crime may be higher in areas such as Limhamn and Västra hamnen, but these are crimes where the police usually do not need to launch massive raids, writes Ardavan Khoshnood, associate professor in emergency medicine at Lund University and criminologist.